Just from personal experience, this sounds completely normal to me. Mine does this with his tongue occasionally when he eats, it looks like some kind of white membraney thing oozing out of the sides of his mouth, as you described. I think they're just adjusting their tongues is all, you shouldn't have anything to worry about unless he starts doing something REALLY weird and something actually detaches from inside him and he pukes it up.
I know it might be hard, but pictures could really help. It sounds normal to me but I haven't seen it, so don't take my word for it. It could be something completely different. D:





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