Sorry to overwelm you, myself and others, I am sure, just want to make sure you have all your options and info.
I am in the same situation, as far as vets go and yes you can put the frogs inside a ziplock or several and preserve them in the frig if you need to or in another area that is cold or even a cooler with ice or icepack, but thats only if want to. It's been my experience hat after a pet dies the store/breeder wants proof or want find the reason it's expired or some owners have posted they have had there animals/frogs examined p.m. to determine the cause of death, especially since they have other frogs and some are sick as well. Knowing the cause may save their remaining frogs.
You obviously don't have to do anything at all, you need to decide whats best for you.
I think at least, the breeder, should be made aware of the fact both the frogs they sold you have expired. If they have any remaining frogs it may save them if they are sick, and you may get replacement frogs.
Again, I am sorry for your losses and don't want to overload you with info, but unfortuneatly this is a time sensitive issue if you do with to presue your case with the breeder.
As far as the water, you could always have it tested. There are kits sold that will tell you whats in your water at hardware store, fish store and many department stores. From what I have been reading, some water may be too purified for your frog, but I am not the expert.






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