I would prioritize pooping over eating. Anytime my girl has been "backed up", she barely eats or refuses food completely, so getting a BM is your best starting point. Are you able to feel or otherwise analyze the right side of his body? You might be able to tell if he has a poop brewing, the right side of his body will feel firm or show a prominent lump.
I'm not sure of the temperature of the water you have him soaking in, but if you haven't already, try letting him sit in some warm water. Better yet, try adding a little honey to it, if you have it on hand. Hopefully one or a few sessions of a nice, warm soak will coax something out of him.
On the other hand, if his right side feels soft and there's no indication of a stool, it may be prudent to bring him into a vet. It's possible he picked up parasites, etc. at some point and was fine when he was healthy, but the stress of a new environment lowered his body's defenses and allowed the invading bodies to get out of hand. However, identifying parasites usually requires a fecal examination, so it's kind of a catch 22. This is me purely guessing on my part, but often times if a frog isn't eating due to impaction or stress, it's because something else (parasites, nematodes, etc.) is hindering his appetite.
To help you feel better about him not eating, my friend bought a baby Pacman that had a month long hunger strike, lol. Frogs can be delicate in some ways, but they are hardy in others, especially horned frogs.





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