It definitely sounds like the male frog is trying to mate with the female frog. If you want the behavior to stop, you'll have to separate them. It's unlikely that the female will be very receptive to mating if you haven't cycled their enclosure, the male will want to mate regardless.

If you wish you can put them together with a large water dish and increased humidity for a week and see if they mate, although be advised this may result in HUNDREDS of froglets.

If not i definitely suggest separating them. If the female is not interested then there is only so much of the male's incursions that she will tolerate and may become defensive and bite him.