Are you talking about osmotic pressure? I doubt there is enough to be of danger to the frog as does any other water that has not had it's salinity adjusted to the salinity of the frogs tissue. If the the only thing in the tank is water, then I might think you have a valid point, but gravel and other things in the viv are quickly going to add the minerals back to the water more so than the frog.
Certainly using distilled water to expand the coco fiber will give it the maximum expansion possible.