Did she clean out the enclosure after she sprayed it? Was it concentrated? I can definitely see that harming a frog. I'm not certain but I know that clove oil can euthanize an amphibian and mint is somewhat numbing at least even though it's safe for humans.
Maybe a soak in pedialyte or other unflavored electralite substance could help him flush out his system if he absorbed the peppermint.
It may just be that the frog arrived sickly and stressed though.





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