I've kept PCFs and I can say I've seen both scenarios, frogs that prefer company and frogs that prefer to be solitary, both in captivity and in the wild... here are a few examples

Name:  DSC00071.JPG
Views: 69
Size:  145.5 KBPCFs number 7, 6 and 5 communing on the apartment drain pipe. These three amigos hung out all the time together, catching bugs drawn by the apartment light.
Name:  DSC00279.JPG
Views: 69
Size:  138.1 KBPCFs number 5 and number 7
Name:  DSC00323--2.jpg
Views: 43
Size:  153.9 KBPCFs number 7 and number 5 (sleeping)
Name:  DSC00474.JPG
Views: 81
Size:  153.5 KBPCFs number 4 and number 2 (house guests this summer in my trailing African violet tank)
Name:  Snapshot 36 (8-9-2014 12-31 AM).png
Views: 49
Size:  294.2 KBPCFs number 1 and number 4
Name:  Two Fat Frogs Napping.png
Views: 80
Size:  277.9 KB PCFs number 2 and number 4
Name:  DSC00043.JPG
Views: 76
Size:  150.7 KBPCFs number 4 and number 1