Looks like it's some left over molt on his abdomen; I've had that happen to some slings on occasion.
What you can do is keep it moist for a while, and try and grab it off with tweezers or something if it does not come off on it's own. I would think it's just barely stuck on, as there are bristles under there.
Otherwise, you can just leave it; it's not anywhere serious that would impede a future molt.
You can "overfeed" a tarantula to a point that it may stop eating or fast for an indeterminate amount of time, but I've only heard/read of one or two reports of them actually eating so much that they seemingly burst.
To be safe, I wouldn't feed it so much to the point where the abdomen is more than double the size of the carapace.
Edit:
Cute 'lil guy, by the way. I miss when mine was that small.





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