Well, that size of aquarium is pretty small for adult red eyes.
Sustaining Dart Frogs on crickets is a challenge unless you have a dependable supply of very small crickets. The one exception is the Golden Poison Dart Frog, Phyllobates terribilis. They eat very large prey, and adults have been known to swallow adult size crickets (though 1/2" crickets are more suitable for adult Golden PDF).
That's a good choice of frog/toad. We're actually in the latter stages of finishing up a comprehensive Care and Breeding Article for fire-bellied toads here on Frog Forum, but it'll be a couple of weeks I think.
They don't really climb so horizontal is best for them. If you lay it out right, I would say 4 in a terrarium that size. Others might say more but 4 would be a comfortable size in my opinion.
They won't hibernate if you keep the temperatures in the early 20s Celsius (70s F), with a permanent water source for them to get in and out of or hang out.
If you want a permanent, filtered water pool in the terrarium, you can't use straight tap water. Boiling only works for water that has only been treated with chlorine. However in many places the municipalities also add ammonia to the water. This combines with chlorine to form chloramines. These won't boil of as easily as chlorine gas. The easiest approach is to use a dechlorinator product like Tetra Aquasafe or Amquel. They're easy to use and ~instantaneous in effect.
Not in the way you are thinking. They are relatively tolerant of each other. Regarding dart frogs and territoriality, many species of dart are not territorial, or at least they are not hostile to others - it just depends on the species of dart.
They are pretty tough. Provide them with a good terrarium, correct temperature range, and a regular food supply and they will do well for you.





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