I'm sure he's gonna take a little while to get used to his new home, especially if it's a wild animal. They don't secret toxins unless severely threatened, usually when picked up by an animals teeth. I have never picked up a toad and had it secret toxin and I've handled a ton of toads, as long as you're gentle you'll see no toxins.
Since you said he ate a lot of worms already, I'm betting that he's full and getting used to his new home so probably won't eat for a little while, just give him some time to settle in. Toads like hiding places, so if you can give him something to hide in or under, it'd make him much more comfortable and he'll settle better.
Edit: Since he's a wild caught toad you can probably use stuff from outside, like pieces of wood, moss, stuff like that. If you can get some clean soil, you could use that as a substrate and he might burrow into it a little bit. I've seen clay pots broken in half used as cool little toad huts, too. Just to give you some ideas.





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