Yes, fighting the pH of your water is a waste of time. Unless you have expensive fish with VERY specific needs (read: Discus) you are just going to fight a losing battle on pH.. most aquarium bred fish and especially aquatic frogs are very adaptable to any normal range of pH (6.5 to 7.5).
I am not familiar with chytrid but that could very easily explain what is happening here. Did you not also have an ADF with a foot that rotted off?? That has to be chytrid of something particularly nasty..





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