Not necessarily. The are plenty of clearly morphologically divergent species with overlapping ranges and intermittent hybridization, including the very icons of evolution, Darwin's finches. Hybridization is not a disqualifier for species status.
So far, we only have evidence that they can sometimes hybridize under captive conditions (potentially with mixed success). They may not hybridize in the wild at all due to slightly different breeding times or preferred congregation areas or call preferences, etc. Even if they do, if the hybrids are strongly weeded out of the gene pool, gene flow will be minimal. Heck, even if the hybrids are just as strong, they could be infertile or just never manage to mate because their call has the wrong frequency for either parent (frog mating responses are *strongly* tuned to specific call frequencies).
However, a bit of googling turned up a conclusive answer, in this paper:
1320 Cranial morphology and karyotypic analysis of Ceratophrys joazeirensis (Anura: Ceratophryidae, Ceratophrynae): taxonomic considerations | Mendeley (full version here:
http://ecoevo.com.br/alunos/ana_paul...otaxa_2006.pdf)
Basically, ornata is octoploid, while cranwelli is diploid. Any hybrid's cells would therefore have unpaired chromosomes, preventing meiosis and rendering the hybrids totally infertile.